In this paper the attention is focused on the numerical study of hyperchaotic 2D-scroll attractors via the Adomian decomposition method. The approach, which provides series solutions of the system equations, is first applied to weakly-coupled Chua's circuits with Hermite interpolating polynomials. Then the method is successfully utilized for achieving hyperchaos synchronization of two coupled Chua's circuits. The reported examples show that the approach presents two main features, i.e., the system nonlinearity is preserved and the chaotic solution is provided in a closed form.