We study relationships between the class of Boolean formulas called exclusive-or expansions based on monotone DNF formulas (MDNF formulas, for short) and the class of Horn DNF formulas. An MDNF formula f is a Boolean formula represented by f = f1fd , where f1 > > fd are monotone DNF formulas and no terms appear more than once. A Horn DNF formula is a DNF formula where each term contains at most one negative literal. We show that the class of double Horn functions, where both f and its negation can be represented by Horn DNF formulas, coincides with a subclass of MDNF formulas such that each DNF formula fi consists of a single term. Furthermore, we give an incrementally polynomial time algorithm that transforms a given Horn DNF formula into the MDNF representation.