Japan encounters an urgent issue of “Carbon Neutrality” as a member of the international world and is required to make the action plans to accomplish this issue, i.e., the zero emission of CO2 by 2050. Our world must change the industries to adapt to the electrification based on the renewable powers. Microwave chemistry is a candidate of electrification of industries for the carbon neutrality on the conditions of usage of renewable energy power generation. This invited paper shows an example of “Microwave Pidgeon process” for smelting magnesium in which heating with burning fossil coals can be replaced with microwave energy for discussing how microwave technology should be developed for that purpose from both the academic and industrial sides.

GaN solid state power amplifiers (SSPA) for wireless power transfer and microwave heating have been reviewed. For wireless power transfer, 9 W output power with 79% power added efficiency at 5.8 GHz has been achieved. For microwave heating, 450 W output power with 70% drain efficiency at 2.45 GHz has been achieved. Microwave power concentration and uniform microwave heating by phase control of multiple SSPAs are demonstrated.

In this study, vertically aligned carbon nanotubes (VA-CNTs) were grown from filler-added LB films with accumulated AlFe2O4 nanoparticles and palmitic acid (C16) as the filler molecule after different hydrogen reduction temperatures of 500°C and 750°C, and the grown VA-CNTs were compared and evaluated. As a result, VA-CNTs were approximately doubled in length after 500°C hydrogen reduction compared to 750°C hydrogen reduction when AlFe2O4 NPs were used. On the other hand, when the catalyst area ratio was decreased by using palmitic acid, i.e., the distance between CNTs was increased, VA-CNTs rapidly shortened after 500°C hydrogen reduction, and VA-CNTs were no longer obtained even in the range where VA-CNTs were obtained in 750°C hydrogen reduction. The inner and outer diameters of VA-CNTs decreased with decreasing catalyst area ratio at 750°C hydrogen reduction and tended to increase at 500°C hydrogen reduction. The morphology of the catalyst nanoparticles after CVD was observed to change significantly depending on the hydrogen reduction temperature and catalyst area ratio. These observations indicate that the state of the catalyst nanoparticles immediately before the CNT growth process greatly affects the physical properties of the CNTs.

In view of the different spatial and temporal resolutions of observed multi-source heterogeneous carbon dioxide data and the uncertain quality of observations, a data fusion prediction model for observed multi-scale carbon dioxide concentration data is studied. First, a wireless carbon sensor network is created, the gross error data in the original dataset are eliminated, and remaining valid data are combined with kriging method to generate a series of continuous surfaces for expressing specific features and providing unified spatio-temporally normalized data for subsequent prediction models. Then, the long short-term memory network is used to process these continuous time- and space-normalized data to obtain the carbon dioxide concentration prediction model at any scales. Finally, the experimental results illustrate that the proposed method with spatio-temporal features is more accurate than the single sensor monitoring method without spatio-temporal features.

In this study, we devised a biofuel cell (BFC) by impregnating sheet-like cellulose nanofiber (CNF) with liquid fuel (fructose) and sandwiching it with the electrodes, making the structure simple and compact. CNF was considered as a suitable material for BFC because it is biocompatible, has a large specific surface area, and exhibits excellent properties as a catalyst and an adsorbent. In this BFC device, graphene-coated carbon fiber woven cloth (GCFC) was used as the material for preparing the electrodes, and the amount of enzyme modification on the surface of each electrode was enhanced. Further, as the distance between the electrodes was same as the thickness of the sheet-shaped CNF, it facilitated the exchange of protons between the electrodes. Moreover, the cathode, which requires an oxidation reaction, was exposed to the atmosphere to enhance the oxygen uptake. The maximum power density of the CNF-type BFC was recorded as 114.5 µW/cm2 at a voltage of 293 mV. This is more than 1.5 times higher than that of the liquid-fuel-type BFC. When measured after 24 h, the maximum power density was recorded as 44.9 µW/cm2 at 236 mV, and the output was maintained at 39% of that observed at the beginning of the measurement. However, it is not the case with general BFCs, where the power generation after 24 h is less than 5%. Therefore, the CNF-type BFCs have a longer lifespan and are fuel efficient.

Improvement of output and lifetime is a problem for biofuel cells. A structure was adopted in which gelation mixed with agarose and fuel (fructose) was sandwiched by electrodes made of graphene-coated carbon fiber. The electrode surface not contacting the gel was exposed to air. In addition, grooves were added to the gel surface to further increase the oxygen supply. The power density of the fuel cell was examined in terms of the electrode area exposed to air. The output increased almost in proportion to the area of the electrode exposed to air. Optimization of the concentration of fuel, gel, and the amount of enzyme at the cathode were also examined. The maximum power density in the proposed system was approximately 121μW/cm2, an enhancement of approximately 2.5 times that in the case of using liquid fuel. For the power density after 24h, the fuel gel was superior to the fuel liquid.

We have measured the Seebeck coefficient of a carbon fabric (CAF) using a homemade measurement system for flexible thermoelectric materials to evaluate Seebeck coefficient along the thickness direction. Our equipment consists of a thermocouple (TC) electrode contacted with a resistive heater and another TC electrode attached to a heat sink. A flexible sample is sandwiched with these TC electrodes and pressed by weights. The equipment is set on a weighing machine in order to confirm and hold the pressing force at the contact between the electrodes and the soft sample. Cu and Pb plates were measured as a reference material to calibrate and clarify the accuracy of our measurement system, and its validity was confirmed. The Seebeck coefficient of a single CAF layer ranged 4.3-5.1 µV/K, independent of extra weight. This fact indicates that the weight of heat sink is enough for stable contact at the TC-electrode/CAF interface. It was found that the Seebeck coefficient of layered CAF increases with an increase in the number of layers, which suggests the influence of the air between the CAF layers even though the heavy weight is used.

We investigated the effects of a bending stress on the change in phase retardation of curved polycarbonate substrates and optical characteristics of flexible liquid crystal displays (LCDs). We clarified that the change in phase retardation was extremely small even for the substrates with a small radius of curvature, because bending stresses occurred in the inner and upper surfaces are canceled each other out. We compensated for the phase retardation of polycarbonate substrates by a positive C-plate and successfully suppressed light leakage in both non-curved and curved states. These results indicate the feasibility of high-quality flexible LCDs using polycarbonate substrates even in curved states.

Many DC commutator motors are widely used in automobiles. In recent years, as compact and high output DC motors have been developed due to advanced technology, the faster the rotational speed is required and the commutation arc causes a high rate of wear/erosion of brush and commutator. Therefore, it is important how the motor speed influences commutation phenomena such as arc duration, residual current and erosion and wear of commutator and brush in order to achieve high reliability and extensive lifespan. In this paper waveforms of commutation voltage and current are measured at the rotation speed of 1000 to 5000min-1and the relation between rotation speed and arc duration / residual current is obtained. In addition long term tests are carried out at the rotation speed of 1000 to 5000min-1 the change of arc duration and effective commutation period is examined during the test of 20hours. Further, brush wear is evaluated by the difference of brush length between before and after test. Consequently, it can be made clear that as the speed increases, the effective commutation period decreases and the arc duration is almost same at the speed up to 3000min-1 and is around 42µsec.

The electron retention characteristics of memory capacitors with blocking oxide-silicon carbonitride (SiCN)-tunnel oxide stacked films were investigated for application in embedded charge trapping nonvolatile memories (NVMs). Long-term data retention in the SiCN memory capacitors was estimated to be more than 10 years at 85 °C. We presented an improved method to analyze the energy distribution of electron trap states numerically. Using the presented analytical method, electron trap states in the SiCN film were revealed to be distributed from 0.8 to 1.3 eV below the conduction band edge in the SiCN band gap. The presence of energetically deep trap states leads us to suggest that the SiCN dielectric films can be employed as the charge trapping film of embedded NVMs.

Optical compensation of flexible in-plane switching (IPS) mode liquid crystal display (LCD) using polycarbonate substrate with uniaxial optical anisotropy was achieved for wide viewing angle. We theoretically clarified that the slow axis of plastic substrate must be parallel to the absorption axis of polarizer and alignment direction of IPS mode LC. We successfully suppressed a light leakage in the dark state in a wide viewing angle range by fabricated device using uniaxial polycarbonate substrates. These results show that it is possible to realize a high quality flexible LCD using plastic substrates.

A gold coated carbon nanotubes composite was used as a contact material in Micro-Electrical-Mechanical-System (MEMS) switches. The switching contact was tested under typical conditions of MEMS relay applications: load voltage of 4 V, contact force of 1 mN, and load current varied between 20-200 mA. This paper focuses on the wear process over switching lifetime, and the dependence of the wear area on the current is discussed. It was shown that the contact was going to fail when the wear area approached the whole contact area, at which point the contact resistance increased sharply to three times the nominal resistance.

A novel fabrication approach for the amperometric biosensor composed of carbon nanotubes (CNT), a plasma-polymerized film (PPF), hexamineruthenium(III)chloride (RU), and enzyme glucose oxidase (GOD) is reported. The configuration of the electrochemical electrode is multilayer films which contain sputtered gold, lower acetonitrile PPF, CNT, RU, GOD, and upper acetonitrile PPF, sequentially. First, PPF deposited on Au acts as a permselective membrane and as a scaffold for CNT layer formation. Second, PPF directly deposited on GOD acts as a matrix for enzyme immobilization. To facilitate the electrochemical communication between the CNT layer and GOD, CNT was treated with nitrogen plasma. The electron transfer mediator RU play a role as the mediator, in which the electron caused by enzymatic reaction transports to the electrode. The synergy between the electron transfer mediator and CNT provides benefits in terms of lowering the operational potential and enhancing the sensitivity (current). The optimized glucose biosensor revealed a sensitivity of 3.4µA mM-1 cm-2 at +0.4V vs. Ag/AgCl, linear dynamic range of 2.5-19mM, and a response time of 6s.

The 4 lowest Transverse-Electric modes of a cylindrical Dielectric Resonator Antenna were investigated using a commercially available simulation software. All 4 modes were shown to produce dipole or multi-pole radiation patterns, having Transverse-Electric polarization as opposed to Transverse-Magnetic as with conventional wire antennas. The even numbered modes were shown to be applicable to the niche application of small Unmanned Aerial Vehicles to ground station communications. A practical design for the lowest order even mode was prepared, and successfully demonstrated on a carbon fiber reinforced plastic ground plane. That design was then shown in simulation to have less adverse interaction when installed on a common small Unmanned Aerial Vehicle airframe at the new 5.05GHz telemetry band than an off-airframe dipole.

Break arcs are generated between carbon contacts in a DC48V and 10A resistive circuit. The external transverse magnetic field formed by a permanent magnet is applied to break arcs. The position of the cathode spot region of the break arcs occurring between carbon contacts is investigated and the following results are shown. The cathode and anode spot regions moves together with and without the magnetic field. The position of the break arcs just before arc extinction tends to shift upward with increase of the magnetic flux density of the transverse magnetic field.

Multi-Walled CNT (MWCNT) are synthesized on a silicon wafer and sputter coated with a gold film. The planar surfaces are mounted on the tip of a piezo-electric actuator and mated with a gold coated hemispherical surface to form an electrical contact. These switching contacts are tested under conditions typical of MEMS relay applications; 4V, with a static contact force of 1mN, at a low current between 20-50mA. The failure of the switch is identified by the evolution of contact resistance which is monitored throughout the switching cycles. The results show that the contact resistance can be stable for up to 120 million switching cycles, which are 106 orders of higher than state-of-the-art pure gold contact. Bouncing behavior was also observed in each switching cycle. The failing mechanism was also studied in relation to the contact surface changes. It was observed that the contact surfaces undergo a transfer process over the switching life time, ultimately leading to switching failure the number of bounces is also related to the fine transfer failure mechanism.

This paper presents symmetric and full swing designs of multiplier and full adder cells, based on weighted inputs for nanotechnology. Carbon Nanotube Field Effect Transistors (CNTFETs) are used to implement the circuits. Proposed designs are simulated using the HSPICE simulation tool and they are compared with their counterparts in terms of delay, power consumption and power-delay product. Significant improvements have been achieved at different voltage levels and different frequencies, load capacitors and temperatures have also been tested. Finally, process variation issue has been analyzed and the results have been reported.

We propose a compact and high-range resolution 76 GHz millimeter-wave radar system for autonomous unmanned helicopters. The purpose of the radar system is to detect and avoid obstacles that may affect the flight safety. To achieve these objectives, a high range resolution and a long detection range are required for the radar systems with small volume and weight. The radar broadband RF front-end module which employs a simple direct conversion method is proposed. The radar module enables the 6 GHz RF signal transmission as well as the output power of about 8 dBm using commercially available low-cost monolithic microwave integrated circuits. The radar system comprises the broadband RF front-end module, a Ku-band local frequency-modulated continuous wave signal synthesizer, and a very light weight carbon fiber reinforced plastic parabolic reflector antenna. The 5 cm of range resolution is experimentally obtained using the 6 GHz RF signal bandwidth. The results of the power line measurement confirm an about 23 dB signal to noise ratio, which is measured from the reflection of the high-voltage power lines about 150 m ahead. In addition, the results of the radar system on-board test using an unmanned helicopter are evaluated. The real-time radar scope, which is transferred through the wireless connection, confirms the detection of the power lines and the other surrounding objects.

A new wideband wave absorber with translucent structure using carbon fibers is presented in this paper. The absorber is composed of bundled short carbon fibers which are arranged in front of a back metal and a spacer. Absorption characteristics of the one-layered absorber showed that matching frequencies can be controlled by the thickness of the spacer and the length of the carbon fibers. To further improve the characteristics, multi-layered absorbers are designed with the same procedure as one-layered absorber. The designed absorber showed 15 dB absorption characteristics from 1.0 to 10.0 GHz. Then a small anechoic chamber with the inside dimension of 200 cm200 cm200 cm was fabricated using ninety-six proposed absorbers. The electrical power in the chamber was measured at 2.45 GHz and the results showed that the variation of the power was less than 4 dB inside a circle with radius of 60 cm as work space for electromagnetic measurements.

A novel fabrication approach for electrochemical sensing of nicotinamide adenine dinucleotide (NADH) using neutral red (NR) functinalized carbon nanotube/plasma-polymerized film composite electrode is reported. The configuration of sensing electrode was NR-functionalized CNTs sandwiched between two acetonitrile PPFs on sputtered gold thin film. The NR as an electron transfer mediator shuttles the electron from the CNT to gold electrode. Due to the synergistic effect between NR and CNT, the resulting electrode showed the lower detection potential and the larger sensitivity (current) than that of NR or CNT alone. The sensor revealed a sensitivity of 29 µA mM-1 cm-2 at +0.15 V vs. Ag/AgCl, linear dynamic range of 0.08–4.2 mM, a detection limit of 18 µM at S/N=3, and a response time of 7 s.